Graphene-based materials in different forms of 0D, 1D, 2D to 3D have proven to be excellent candidates of electrode materials in electrochemical energy storage systems, such as supercapacitors.
The graphene-based materials are promising for applications in supercapacitors and other energy storage devices due to the intriguing properties, i.e., highly tunable surface area, outstanding electrical conductivity, good chemical stability and excellent mechanical behavior.
Since Stoller described the first graphene supercapacitor in 2008, significant developments have been made during this last decade in the development of new graphene-based electrodes.
To fabricate supercapacitors with free-standing graphene particles, slurry casting method was generally employed, in which the active material powders were mixed with polymer binder and conductive additives to connect electrode material with current collectors.
A similar but more limited study in 2020 compared graphene and activated carbon to show that the specific capacitance of graphene-based supercapacitors was markedly lower than that of activated carbon, likely due to the presence of graphene oxide.
Graphene-based supercapacitors are more expensive. Because graphene-based supercapacitors are a newer technology, their production has not yet reached economies of scale. Furthermore, due to more stringent quality requirements, graphene continues to be more expensive to produce than activated carbon.
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